高等無機化學(一) 課程大綱
Syllabus on Advanced Inorganic Chemistry (I)
Scope
Bonding, Structure, Reactivity, Mechanism, and Applications of Inorganic Compounds
Outline
I. Symmetry & Bonding
Point groups & Molecular Geometry, Symmetry Elements & Operations, Point Groups, Representation & Character Tables, Applications to Spectroscopies
Valence Bond Theory
VSEPR, EAN Rule, Resonance, Hybridization, Bond Characters, Acid-Base Concept
Molecular Orbital theory
LCAO, SALC, Diatomic & Multicenter Compounds, Walsh Diagram
II. Transition Metal Chemistry
Transition Metal Elements
Electronic Configuration, Spectroscopy, Magnetism
Coordination Chemistry
Bonding, Structures, Reactivity & Reaction Mechanisms
Supramolecular Chemistry & Organometallic Chemistry
A Brief Introduction on Modern Development
III. Main Group Chemistry
Thermodynamics
Stability in Solutions vs. Solid State Systems
Structures & Reactivity
教科書
Suggested References
1. F. Albert Cotton; `Chemical Applications of Group theory`; Wiley-Interscience; 1990; 3rd Edition.
2. James E. Huheey, Ellen A. Keiter, Richard L. Keiter; `Inorganic Chemistry: Principles of Structure and Reactivity`; Benjamin Cummings; 1997; 4th Edition.
3. F. Albert Cotton, Geoffrey Wilkinson, Carlos A. Murillo, Manfred Bochmann, Russel . Grimes; `Advanced Inorganic Chemistry`; Wiley-Interscience; 1999; 6th Edition.
評量方式
Grading Total 100%.
1. Assignments, Homework, Term Paper and/or Presentation, 33%
2. One Midterm Examination, 33%
3. One Final Examination, 34%
先修科目
Pre-requistes
1. General Chemistry
2. Inorganic Chemistry, Undergraduate Level
上課方式
Means of Conducting the Course
Lectures and Discussion